Why do aromatic interactions matter of compound: 3326-71-4

As far as I know, this compound(3326-71-4)Name: 2-Furoic hydrazide can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Qian, Hengyu; Yu, Shuyan; Song, Liping; Zhang, Tongyan; Yin, Zhigang; Zhao, Feng; Yang, Jiale; Wang, Caihong published an article about the compound: 2-Furoic hydrazide( cas:3326-71-4,SMILESS:O=C(C1=CC=CO1)NN ).Name: 2-Furoic hydrazide. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:3326-71-4) through the article.

Four new palladium pincer complexes I (R = H, 3-OMe, 3-OEt, 5-Cl) incorporating ONO type furoylhydrazone ligands have been prepared in good yields. These palladium complexes were structurally characterized by elemental anal., IR, 1H- and 13C-NMR spectra. X-ray single crystal analyses of Pd1-Pd4 revealed that the metal center adopted a slightly distorted square planar geometry in which the hydrazone bound the metal ion via the phenolic-O, azomethine-N and imidolate-O atoms. Using these ONO pincer complexes as catalyst, excellent yields of biaryls could be obtained for coupling of arylboronic acids with aryl bromides at a low catalyst loading (0.01 mol%).

As far as I know, this compound(3326-71-4)Name: 2-Furoic hydrazide can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics