Recommanded Product: 610-09-3. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about Nitroaromatic detecting zinc cyclohexyldicarboxylate coordination polymers with a long spanning dipyridyl tethering ligand. Author is LaDuca, Andrew R.; Przybyla, Jack J.; Porta, Angela R.; LaDuca, Robert L..
Four new divalent Zn coordination polymers containing a dianionic cyclohexyldicarboxylate and the long-spanning pillaring dipyridyl ligand bis(4-pyridylmethyl)piperazine (bpmp) were prepared and structurally characterized via single-crystal x-ray diffraction. Significant structural and topol. diversity across the series is evident. {[Zn2(cis-12cdc)2(bpmp)]·6H2O}n (1, cis-12cdc = cis-1,2-cyclohexanedicarboxylate) shows a coordination polymer layer motif with embedded paddlewheel {Zn2(OCO)4} dinuclear units and T6(4)4(4) classification H2O tapes. Using cis-1,2-cyclohex-4-enedicarboxylate (cis-12chedc) afforded [Zn2(cis-12chedc)2(bpmp)(H2O)2]n (2), which manifests a simple yet unusual (6)(648.10) topol. [Zn2(cis-13cdc)2(bpmp)]n (3, cis-13cdc = cis-1,3-cyclohexanedicarboxylate) displays sawtooth (4,4) coordination polymer layers, while [Zn2(trans-14cdc)2(bpmp)]n (4, trans-14cdc = trans-1,4-cyclohexanedicarboxylate) shows a 3-dimensional system of coordination polymer networks with 3-fold interpenetrated 41263pcu topol. The layered phases 1-3 showed capability for the detection of small quantities of nitrobenzene in EtOH suspension.
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