So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Pi-Boleda, Bernat; Sans, Marta; Campos, Maria; Nolis, Pau; Illa, Ona; Estevez, Juan Carlos; Branchadell, Vicenc; Ortuno, Rosa M. researched the compound: cis-Cyclohexane-1,2-dicarboxylic acid( cas:610-09-3 ).Product Details of 610-09-3.They published the article 《Studies on Cycloalkane-Based Bisamide Organogelators: A New Example of Stochastic Chiral Symmetry-Breaking Induced by Sonication》 about this compound( cas:610-09-3 ) in Chemistry – A European Journal. Keywords: cycloalkane based bisamide organogelator stochastic chiral symmetry breaking sonication; chirality; cycloalkane bisamides; physical asymmetric-induction; self-assembly; symmetry breaking; ultrasound. We’ll tell you more about this compound (cas:610-09-3).
Enantiomerically pure C16-alkyl amides derived from cis and trans cycloalkane-1,2-dicarboxylic acids, resp., have been synthesized and their behavior as organogelators has been investigated. These compounds include cis/trans diastereomeric cyclobutane and cyclohexane derivatives with the aim to explore the influence of the ring size as well as the relative configuration in their hierarchical self-assembly to form gels. High resolution 1H NMR spectroscopy studies allowed the determination of the dynamics of the gelation process in [D8]toluene and the sol-gel transition temperature The morphol. and size of the aggregates have been investigated and results have shown that, in the case of cyclobutane derivatives, the cis/trans stereochem. is not relevant for the gelation behavior and the properties of the soft-materials obtained, but it is remarkable for cyclohexane diamides, which are better organogelators. The four compounds produce chiral aggregates despite that two of them are meso achiral mols. We show herein that this fact is an example of stochastic symmetry breaking induced by sonication. The self-assembly of these mols. has been modelled providing information and support about the structure and the chirality of the aggregates.
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Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics