Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Polyhedron called Nitroaromatic detecting zinc cyclohexyldicarboxylate coordination polymers with a long spanning dipyridyl tethering ligand, Author is LaDuca, Andrew R.; Przybyla, Jack J.; Porta, Angela R.; LaDuca, Robert L., which mentions a compound: 610-09-3, SMILESS is O=C([C@H]1[C@@H](C(O)=O)CCCC1)O, Molecular C8H12O4, Reference of cis-Cyclohexane-1,2-dicarboxylic acid.
Four new divalent Zn coordination polymers containing a dianionic cyclohexyldicarboxylate and the long-spanning pillaring dipyridyl ligand bis(4-pyridylmethyl)piperazine (bpmp) were prepared and structurally characterized via single-crystal x-ray diffraction. Significant structural and topol. diversity across the series is evident. {[Zn2(cis-12cdc)2(bpmp)]·6H2O}n (1, cis-12cdc = cis-1,2-cyclohexanedicarboxylate) shows a coordination polymer layer motif with embedded paddlewheel {Zn2(OCO)4} dinuclear units and T6(4)4(4) classification H2O tapes. Using cis-1,2-cyclohex-4-enedicarboxylate (cis-12chedc) afforded [Zn2(cis-12chedc)2(bpmp)(H2O)2]n (2), which manifests a simple yet unusual (6)(648.10) topol. [Zn2(cis-13cdc)2(bpmp)]n (3, cis-13cdc = cis-1,3-cyclohexanedicarboxylate) displays sawtooth (4,4) coordination polymer layers, while [Zn2(trans-14cdc)2(bpmp)]n (4, trans-14cdc = trans-1,4-cyclohexanedicarboxylate) shows a 3-dimensional system of coordination polymer networks with 3-fold interpenetrated 41263pcu topol. The layered phases 1-3 showed capability for the detection of small quantities of nitrobenzene in EtOH suspension.
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Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics