Category: 37443-42-8

Quality Control of Methyl tetrahydrofuran-2-carboxylate. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Antitumor activity of SRI 62-834, a cyclic ether analog of ET-18-OCH3. Author is Houlihan, William J.; Lee, Mark L.; Munder, Paul G.; Nemecek, Georgina M.; Handley, Dean A.; Winslow, Christine M.; Happy, John; Jaeggi, Christian.

SRI 62-834 (I), an analog of the antitumor agent ET-18-OCH3 in which the O atom at C atom 2 was incorporated into a 5-membered heterocycle, was prepared and exhibited good cytotoxicity in vitro against a variety of tumor cell lines and was as effective as Et-18-OCH3 given orally to mice with Meth A sarcomas. SRI 62-834 inhibited platelet-derived growth factor, possibly at the receptor level, and platelet-activating factor at the receptor level.

In addition to the literature in the link below, there is a lot of literature about this compound(Methyl tetrahydrofuran-2-carboxylate)Quality Control of Methyl tetrahydrofuran-2-carboxylate, illustrating the importance and wide applicability of this compound(37443-42-8).

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 37443-42-8, is researched, Molecular C6H10O3, about Divergent Reactivity during the Trapping of Benzynes by Glycidol Analogs: Ring Cleavage via Pinacol-Like Rearrangements vs Oxirane Fragmentations, the main research direction is benzyne trapping glycidol analog hydro cyclic ether reactivity.SDS of cas: 37443-42-8.

Hydroxy-containing cyclic ethers react with thermally generated benzynes to produce aryl ethers. Diverse reactivity was observed Cleavage of the cyclic ether was involved in most of the pathways. The transformations are rationalized via initial formation of oxonium ion-containing 1,3-zwitterions arising from preferential nucleophilic attack on the benzyne by the ether oxygen. Pinacol-like rearrangements, including ring expansion, to yield aldehydes or ketones and oxirane fragmentations to generate aryl enol ethers were main competing events.

In addition to the literature in the link below, there is a lot of literature about this compound(Methyl tetrahydrofuran-2-carboxylate)SDS of cas: 37443-42-8, illustrating the importance and wide applicability of this compound(37443-42-8).

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Product Details of 37443-42-8. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Donor-Acceptor Complex Enables Alkoxyl Radical Generation for Metal-Free C(sp3)-C(sp3) Cleavage and Allylation/Alkenylation.

The alkoxyl radical is an essential and prevalent reactive intermediate for chem. and biol. studies. Here we report the first donor-acceptor complex-enabled alkoxyl radical generation under metal-free reaction conditions induced by visible light. Hantzsch ester forms the key donor-acceptor complex with N-alkoxyl derivatives, which is elucidated by a series of spectrometry and mechanistic experiments Selective C(sp3)-C(sp3) bond cleavage and allylation/alkenylation is demonstrated for the first time using this photocatalyst-free approach with linear primary, secondary, and tertiary alkoxyl radicals.

This literature about this compound(37443-42-8)Product Details of 37443-42-8has given us a lot of inspiration, and I hope that the research on this compound(Methyl tetrahydrofuran-2-carboxylate) can be further advanced. Maybe we can get more compounds in a similar way.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Computed Properties of C6H10O3. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Catalytic hydrogenation of furan derivatives. 8. The behavior of products with the passage of the reaction time. Author is Shinozaki, Kohichi; Abe, Mitsuyuki; Uchiyama, Midori.

Hydrogenation of I in R1OH (R1 = lower alkyl) in the presence of Pd black or PdO was studied. I (R = H, Me) over Pd black formed small amounts of intermediate by-product ketals (II), which were hydrogenolyzed to the main products (III). With PdO, considerable amounts of II were formed from I (R = H, Me, CH:CHCO2Me, CO2Me). The amount of II formed decreased with increasing size of both R and R1.

In addition to the literature in the link below, there is a lot of literature about this compound(Methyl tetrahydrofuran-2-carboxylate)Computed Properties of C6H10O3, illustrating the importance and wide applicability of this compound(37443-42-8).

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Research Support, Non-U.S. Gov’t, Chirality called The enzymatic resolution of 1-(4-chlorophenyl)ethylamine by Novozym 435 to prepare a novel triazolopyrimidine herbicide, Author is Zhang, Yinjun; Cheng, Feifei; Yan, Hongde; Zheng, Jianyong; Wang, Zhao, which mentions a compound: 37443-42-8, SMILESS is O=C(C1OCCC1)OC, Molecular C6H10O3, Recommanded Product: Methyl tetrahydrofuran-2-carboxylate.

The kinetic resolution of (R,S)-1-(4-chlorophenyl)ethylamine was accomplished using a com. lipase from Candida antarctica (Novozym 435). The performance of this lipase was investigated for the enantioselective amidation of (R,S)-1-(4-chlorophenyl)ethylamine, leaving the target product (S)-1-(4-chlorophenyl)ethylamine in its unreacted form. The effects of various types of solvents and an acyl donor, the molar ratio of the substrate to the acyl donor, and the reaction temperature were studied. The optimum reaction conditions were found to result in amidation with Me 2-tetrahydrofuroate at 40°C in Me tert-Bu ether, with a substrate/acyl donor molar ratio of 1:2.4. The conversion rate of (R,S)-1-(4-chlorophenyl)ethylamine was 52%, with an enantiomeric excess of 99% towards the unreacted substrate in a reaction time of 22 h. Finally, using optically pure (S)-1-(4-chlorophenyl)ethylamine as the raw material, the chem. synthesis of (S)-N-(1-(4-chlorphenyl)ethyl)-2-(5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-2-ylthio)acetamide, a novel triazolopyrimidine herbicide, was achieved, and the total yield and purity were 83.5% and 95.3%, resp.

In addition to the literature in the link below, there is a lot of literature about this compound(Methyl tetrahydrofuran-2-carboxylate)Recommanded Product: Methyl tetrahydrofuran-2-carboxylate, illustrating the importance and wide applicability of this compound(37443-42-8).

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Hydroformylation of furan compounds in the presence of cobalt catalysts》. Authors are Mistrik, E. J..The article about the compound:Methyl tetrahydrofuran-2-carboxylatecas:37443-42-8,SMILESS:O=C(C1OCCC1)OC).Formula: C6H10O3. Through the article, more information about this compound (cas:37443-42-8) is conveyed.

The hydroformylation of furans, e.g., 2-methylfuran, furfural, Me 2-furanacrylate and Me 2-furancarboxylate, in the presence of Co2(CO)8 and Co2(CO)7(PPh3)2 was studied. In addition to the products of hydroformylation, hydrogenation products were identified. The relative reactivity of the furans was estimated and a reaction mechanism proposed.

In addition to the literature in the link below, there is a lot of literature about this compound(Methyl tetrahydrofuran-2-carboxylate)Formula: C6H10O3, illustrating the importance and wide applicability of this compound(37443-42-8).

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Name: Methyl tetrahydrofuran-2-carboxylate. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about An efficient synthesis of 3,4-dihydropyridone via a tandem olefin isomerization-ring-closing metathesis reaction. Author is Si, Chong; Fales, Kevin R.; Boyer, Robert D.; George Njoroge, F..

Novel 3,4-dihydropyridones were efficiently prepared via a tandem olefin isomerization-ring-closing metathesis reaction catalyzed by the second-generation Grubbs catalyst. The products were further functionalized at the 5-position, providing an interesting structural motif to be evaluated in medicinal chem.

In addition to the literature in the link below, there is a lot of literature about this compound(Methyl tetrahydrofuran-2-carboxylate)Name: Methyl tetrahydrofuran-2-carboxylate, illustrating the importance and wide applicability of this compound(37443-42-8).

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Nikishin, G. I.; Glukhovtsev, V. G.; Peikova, M. A.; Maksimova, N. G. published an article about the compound: Methyl tetrahydrofuran-2-carboxylate( cas:37443-42-8,SMILESS:O=C(C1OCCC1)OC ).Category: benzisoxazole. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:37443-42-8) through the article.

Liquid phase oxidation of tetrahydrofurfuryl alc., its formate and acetate, and Me 2-tetrahydrofurancarboxylate, largely at 115°, in 10-25 hr in a flow-type glass reactor gave good yields of γ-butyrolactone or its γ-CH2OH, CH2O2CH, CH2OAc or CO2Me derivatives, resp., HCO2H and succinic acid. Evidently the oxidation occurred at the C2 and C5 positions. Uv light promoted the reaction and allowed its operation at lower temperature The summary yields of the lactones were 72-95%. The last substrate above was oxidized in the presence of Mn(OAc)2.4H2O catalyst at 70°.

In addition to the literature in the link below, there is a lot of literature about this compound(Methyl tetrahydrofuran-2-carboxylate)Category: benzisoxazole, illustrating the importance and wide applicability of this compound(37443-42-8).

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Quality Control of Methyl tetrahydrofuran-2-carboxylate. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Hydroformylation of furan compounds in the presence of cobalt catalysts. Author is Mistrik, E. J..

The hydroformylation of furans, e.g., 2-methylfuran, furfural, Me 2-furanacrylate and Me 2-furancarboxylate, in the presence of Co2(CO)8 and Co2(CO)7(PPh3)2 was studied. In addition to the products of hydroformylation, hydrogenation products were identified. The relative reactivity of the furans was estimated and a reaction mechanism proposed.

There are many compounds similar to this compound(37443-42-8)Quality Control of Methyl tetrahydrofuran-2-carboxylate. if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Formula: C6H10O3. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Donor-Acceptor Complex Enables Alkoxyl Radical Generation for Metal-Free C(sp3)-C(sp3) Cleavage and Allylation/Alkenylation. Author is Zhang, Jing; Li, Yang; Xu, Ruoyu; Chen, Yiyun.

The alkoxyl radical is an essential and prevalent reactive intermediate for chem. and biol. studies. Here we report the first donor-acceptor complex-enabled alkoxyl radical generation under metal-free reaction conditions induced by visible light. Hantzsch ester forms the key donor-acceptor complex with N-alkoxyl derivatives, which is elucidated by a series of spectrometry and mechanistic experiments Selective C(sp3)-C(sp3) bond cleavage and allylation/alkenylation is demonstrated for the first time using this photocatalyst-free approach with linear primary, secondary, and tertiary alkoxyl radicals.

There are many compounds similar to this compound(37443-42-8)Formula: C6H10O3. if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics