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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about Studies on Cycloalkane-Based Bisamide Organogelators: A New Example of Stochastic Chiral Symmetry-Breaking Induced by Sonication.Recommanded Product: 610-09-3.

Enantiomerically pure C16-alkyl amides derived from cis and trans cycloalkane-1,2-dicarboxylic acids, resp., have been synthesized and their behavior as organogelators has been investigated. These compounds include cis/trans diastereomeric cyclobutane and cyclohexane derivatives with the aim to explore the influence of the ring size as well as the relative configuration in their hierarchical self-assembly to form gels. High resolution 1H NMR spectroscopy studies allowed the determination of the dynamics of the gelation process in [D8]toluene and the sol-gel transition temperature The morphol. and size of the aggregates have been investigated and results have shown that, in the case of cyclobutane derivatives, the cis/trans stereochem. is not relevant for the gelation behavior and the properties of the soft-materials obtained, but it is remarkable for cyclohexane diamides, which are better organogelators. The four compounds produce chiral aggregates despite that two of them are meso achiral mols. We show herein that this fact is an example of stochastic symmetry breaking induced by sonication. The self-assembly of these mols. has been modelled providing information and support about the structure and the chirality of the aggregates.

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Formula: C8H12O4. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about Potassium selectivities of bis(benzo-15-crown-5) derivatives obtained from cyclohexanedicarboxylic acids. Author is Kimura, Keiichi; Ishikawa, Atsuo; Tamura, Hiroshi; Shono, Toshiyuki.

Several bis(benzo-15-crown-5) derivatives containing a cyclohexane or benzene ring in the bridge chain were synthesized as neutral carriers of coated-wire K+-selective electrodes. The bis(benzocrown ether) derivative obtained from cis-1,2-cyclohexanedicarboxylic acid was outstandingly K-selective.

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COA of Formula: C8H12O4. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about 3,8-Thionanedione 1,1-dioxide. Synthesis and solid-state conformation. Author is Quin, Louis D.; Leimert, John; Middlemas, Eric D.; Miller, Richard W.; McPhail, Andrew T..

The title compound is conventiently prepared in 80% overall yield by ozonolysis at -78°C of the cycloadduct of SO2 with 1,2-dimethylenecyclohexane. Single-crystal X-ray anal. establishes that the nine-membered ring adopts a twist-chair-chair conformation in which the S and the mid-point of the C(5)-C(6) bond lie on a noncrystallog. C2 axis, but the ring shape differs significantly from that of cyclononane in order to accommodate transannular dipole…dipole interactions.

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The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Condensation of aromatic aldehydes with glycine and acetylglycine》. Authors are Dakin, H. D..The article about the compound:cis-Cyclohexane-1,2-dicarboxylic acidcas:610-09-3,SMILESS:O=C([C@H]1[C@@H](C(O)=O)CCCC1)O).Recommanded Product: cis-Cyclohexane-1,2-dicarboxylic acid. Through the article, more information about this compound (cas:610-09-3) is conveyed.

The condensation referred to in the title is complicated by a competing reaction between CH2(NH2)CO2H and BzH, forming a non-acetylated derivative possibly of a type resembling a Schiff base. The 2 reactions are shown thus: (1) H2NCH2CO2H → AcNHCH2CO2H → MeC:N.C(:CHPh).CO.O → MeCONHC(:CHPh)CO2H, (2) HO2CCH2NH2 + BzH → HO2CCH2N:-CHPh (I) or O.CO.CH2.NH.CHPh. I may be called benzylideneglycine and was isolated and analyzed. Because the 2nd condensation product is a non-acetylated compound its formation can be largely suppressed by acetylating the glycine before the reaction. Correspondingly larger yields of the azlactone of α-acetamidocinnamic acid were obtained. Acetylation was most easily effected by warming glycine suspended in 3 parts of glacial AcOH with the theoretical amount of Ac2O until solution was obtained. A variety of aldehydes was used although the product from salicyl aldehyde was the most interesting. AcOC6H4CH:C.N:CMe.O.CO (II) → HOC3H4CH:C(NHAc)CO2H (III) → O.C6H4.CH:C(NHAc).CO (IV). II on treating with alkali and subsequent acidification forms the transient III which quickly passes over to IV. Detailed exptl. data are given.

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Recommanded Product: cis-Cyclohexane-1,2-dicarboxylic acid. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about The effects of cis-trans configuration of cyclohexane multi-carboxylic acids on colloidal forces in dispersions: steric, hydrophobic and bridging. Author is Chandramalar, A. V. M.; Lim, Y. Y.; Leong, Y. K..

The effects of cis- and trans-1,2-, trans-1,4-cyclohexanedicarboxylic acid, 95% cis-1,3,5-cyclohexane tricarboxylic acid and cis-1,2,3,4,5,6-cyclohexanehexacarboxylic acid on the yield stress-pH behavior of concentrated ZrO2 dispersions are reported. Adsorbed cis-1,2,3,4,5,6-cyclohexanehexacarboxylic acid imparts predominantly steric interactions. It forms a steric barrier keeping the interacting particles apart. Adsorbed cis- and trans-1,2 increase the maximum yield stress and this was attributed to a hydrophobic force resulting from the part of the cyclohexane ring sticking out into the solution which is devoid of charged or hydrophilic group. Adsorbed trans-1,4 increases the maximum yield stress by ≥3-fold and its configuration favors strong bridging interaction with an adjacent particle. Predominantly, cis-1,3,5 also increases the maximum yield stress but only by 60% at the same additive concentration This was attributed to a smaller degree of bridging.

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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, CrystEngComm called Construction of coordination frameworks based on 4-imidazolyl tecton 1,4-di(1H-imidazol-4-yl)benzene and varied carboxylic acids, Author is Chen, Shui-Sheng; Zhao, Yue; Fan, Jian; Okamura, Taka-aki; Bai, Zheng-Shuai; Chen, Zhi-Hao; Sun, Wei-Yin, which mentions a compound: 610-09-3, SMILESS is O=C([C@H]1[C@@H](C(O)=O)CCCC1)O, Molecular C8H12O4, Recommanded Product: 610-09-3.

Nine new coordination polymers [Mn(L)(OX)] (1), [Zn(L)(MBDC)] (2), [Zn(L)(BPDA)] (3), [Co3(L)2(BTA)2]·2H2O (4), [Co2(L)2(BTCA)]·2H2O (5), [Ni(L)(e,a-cis-1,2-CHDC)]·2H2O (6), [Co(L)(e,a-cis-1,4-CHDC)] (7), [Co(L)(e,e-trans-1,4-CHDC)]·2H2O (8) and [Co(L)(e,e,e-cis-1,3,5-HCHTC)]·0.45H2O (9) were obtained by reactions of varied metal salts with 1,4-di(1H-imidazol-4-yl)benzene (L) in the presence of corresponding auxiliary ligands of oxalic acid (H2OX), 5-methyl-1,3-benzenedicarboxylic acid (H2MBDC), 4,4′-biphenyldicarboxylic acid (H2BPDA), benzene-1,3,5-triacetic acid (H3BTA), 1,2,4,5-benzenetetracarboxylic acid (H4BTCA), cis-1,2-cyclohexanedicarboxylic acid (cis-1,2-H2CHDC), cis-/trans-1,4-cyclohexanedicarboxylic acid (cis-/trans-1,4-H2CHDC) and cis-1,3,5-cyclohexane tricarboxylic acid (cis-1,3,5-H3CHTC), resp. Complex 1 has a one-dimensional (1D) chain structure and 2 has a two-dimensional (2D) network with 63-hcb topol. Complex 3 is a complicated uninodal 4-connected three-dimensional (3D) net with Point (Schlaefli) symbol (4.6.83·10)(4.63·82)(63·103)(64·82) while 4 is a (3,8)-connected tfz-d 3D net with Point (Schlaefli) symbol (43)2(46·618·84) based on the trinuclear Co(II) secondary building units (SBUs). Complex 5 is a 3-fold interpenetrating mog net with Point (Schlaefli) symbol of (4.64·8)2(42·62·82), while 6 is a 2D net with (4,4) topol. based on binuclear SBUs. In contrast to the 2D network of 7 with e,a-cis-1,4-CHDC2-, 8 with e,e-trans-1,4-CHDC2- is a 5-fold interpenetrating 66-dia 3D net. Complex 9 has a 1D ladder-like chain structure with a stable conformation from the e,e,e-cis-1,3,5-HCHTC2- ligand. Complexes 2 and 3 exhibit intense light blue emission in the solid state at room temperature and the results of magnetic measurements showed that there are antiferromagnetic interactions in 1.

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New downstream synthetic route of 610-09-3

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Bi, Shuangyu; Yu, Daqi; Si, Guangwei; Luo, Chunxiong; Li, Tongqing; Ouyang, Qi; Jakovljevic, Vladimir; Sourjik, Victor; Tu, Yuhai; Lai, Luhua researched the compound: cis-Cyclohexane-1,2-dicarboxylic acid( cas:610-09-3 ).Formula: C8H12O4.They published the article 《Discovery of novel chemoeffectors and rational design of Escherichia coli chemoreceptor specificity》 about this compound( cas:610-09-3 ) in Proceedings of the National Academy of Sciences of the United States of America. Keywords: Escherichia Tar chemoreceptor specificity design chemoeffector chemoattractant. We’ll tell you more about this compound (cas:610-09-3).

Bacterial chemoreceptors mediate chemotactic responses to diverse stimuli. Here, by using an integrated in silico, in vitro, and in vivo approach, we screened a large compound library and found eight novel chemoeffectors for the Escherichia coli chemoreceptor Tar. Six of the eight new Tar binding compounds induce attractant responses, and two of them function as antagonists that can bind Tar without inducing downstream signaling. Comparison between the antagonist and attractant binding patterns suggests that the key interactions for chemotaxis signaling are mediated by the hydrogen bonds formed between a donor group in the attractant and the main-chain carbonyls (Y149 and/or Q152) on the α4 helix of Tar. This mol. insight for signaling is verified by converting an antagonist to an attractant when introducing an N-H group into the antagonist to restore the hydrogen bond. Similar signal triggering effect by an O-H group is also confirmed. Our study suggests that the Tar chemoeffector binding pocket may be separated into two functional regions: region I mainly contributes to binding and region II contributes to both binding and signaling. This scenario of binding and signaling suggests that Tar may be rationally designed to respond to a non-native ligand by altering key residues in region I to strengthen binding with the novel ligand while maintaining the key interactions in region II for signaling. Following this strategy, we have successfully redesigned Tar to respond to L-arginine, a basic amino acid that does not have chemotactic effect for WT Tar, by two site-specific mutations (R69’E and R73’E).

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The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about Neel temperature enhancement by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials, the main research direction is manganese cyclohexane cyclhexene dicarboxylate hybrid material crystal structure magnetism.Formula: C8H12O4.

Three inorganic-organic hybrid compounds, [MnII4(trans-1,2-chdc)4(H2O)]·0.25H2O, [MnII2(cis-1,2-chdc)2] and [MnII3(μ3-OH)2(1,2-chedc)2], were hydrothermally synthesized by controlling the conformation of cyclohexane-1,2-dicarboxylate (chdc) and cyclohex-1-ene-1,2-dicarboxylate (chedc), and characterized by x-ray crystallog. and magnetic measurements. These compounds have different infinite inorganic Mn-O layers with an interesting effect of the in-plane magnetic correlation on the Neel temperature

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Recommanded Product: 610-09-3. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about Coordination preference of 1,2-bis((1H-imidazole-1-yl)methyl)benzene and different carboxylate ligands with transition metal ions directed by weak interactions.

Three novel metal-organic complexes, formulated as [Cu2(2-HBA)2(bimb)4] (1), {[Cd(CEDA)(bimb)]·H2O}n (2), and {[Ag2(bimb)2]·(1,4-CDA)·13H2O} (3) (bimb = 1,2-bis((1H-imidazole-1-yl)methyl)benzene; 2-HBA = 2-hydroxybenzoic acid; CEDA = cyclohex-4-ene-1,2-dicarboxylic acid; 1,4-CDA = cyclohexane-1,4-dicarboxylic acid), were synthesized by self-assembly of mixed ligands with Cu(II), Cd(II), and Ag(I) under hydrothermal conditions and characterized by means of single-crystal X-ray diffraction, X-ray powder diffraction, IR spectra, thermogravimetric anal., fluorescence spectra and UV-vis absorption spectra. 1 Is shown as a 0D structure, which is formed by Cu2+, 2-HBA ligands and bimb ligands. 2 Displays a 1D ladder structure, which is built by Cd2+, CEDA ligands and bimb ligands, and it is assembled into 2D structure by hydrogen bonding. 3 Possesses a 0D [Ag(bimb)]2 dimer which is assembled into 3D structure by the Ag-O weak interaction and hydrogen bonding. Interestingly, a rare 13-core water cluster participates in forming the network of 3. The UV-vis spectrum and luminescence properties were also studied and discussed.

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The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: cis-Cyclohexane-1,2-dicarboxylic acid(SMILESS: O=C([C@H]1[C@@H](C(O)=O)CCCC1)O,cas:610-09-3) is researched.Recommanded Product: 610-09-3. The article 《Synthesis and properties of some basic metals and manganese salts of cis-1,2-cyclohexane dicarboxylic acid》 in relation to this compound, is published in Asian Journal of Chemistry. Let’s take a look at the latest research on this compound (cas:610-09-3).

Sodium, potassium, ammonium and manganese salts of cis-1,2-cyclohexanedicarboxylic acid were synthesized. The structural characteristics of these salts were analyzed by thermog. and spectroscopic methods and examined on liver and wheat under the effect of their biol. activities. They can be used as a micro-fertilizer in the fields biol. and agriculture.

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