Application In Synthesis of Methyl tetrahydrofuran-2-carboxylate. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Electrochemical fluorination of several esters derived from oxolane-2-yl-carboxylic acid, oxolane-2-yl-methanol and oxane-2-yl-methanol. Author is Abe, Takashi; Tamura, Masanori; Sekiya, Akira.
Electrochem. fluorination (ECF) of ester derivatives of (tetrahydro-2-furanyl)carboxylic acid (I), (tetrahydro-2-furanyl)methanol (II) and (2-oxanyl)methanol (III) were investigated. Perfluoro oxolane carbonyl fluoride was obtained from derivatives of I and II, and perfluoro(oxane-2-yl-carbonyl fluoride) was obtained from derivatives of III as the desired compounds, resp. From the ECF of acetates, perfluoro-spiro-ether derivatives having a dioxolane ring were also obtained as the cyclization product in low yield together with a perfluoro acid fluoride. The structure of these perfluoro-spiro-ether derivatives was confirmed by analyzing the chlorinated products, which were obtained by the reaction with AlCl3.
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Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics